Vanilla chemistry

What you wanted to know on vanilla

Vanilla sensory differences Danisco

How do vanilla’s from different origins compare?

The future of natural vanilla! IFF

Food Product design on vanilla creation

Vanilla recipes Using natural vanilla extracts

Vanilla    New book on all aspects of vanilla

Vanilla and its use in perfumery

USA standards for vanilla extracts

Vanilla Curing Technologies

Vanilla Report Reunion

Red label quality

Indian Vanilla curing

Venui Vanilla

PNG Vanilla is just as exotic as  its people.

Grown in rainforests and picked by hand..Extracts are now available!

PNG Vanilla Extracts    click for details!

Vanilla Recipes

Some great recipes on this site

Vanilla Sugar

To make vanilla sugar, simply follow these five steps:

1. Split one vanilla bean in half and scrape the seeds from each half

2. Cut the two halves into about ½" pieces.

3. Add the pieces and the seeds to three cups of granulated sugar in a glass jar.

4. Tightly close and store for one week, shaking occasionally.

5. Sieve the sugar as you use it, returning the beans and seeds to the jar. Add more sugar to the jar. This may be repeated over and over for 6 months or so, or until the flavor of the vanilla sugar weakens.

Recommended applications:
Flavoring for cereals, French toast, or fruit and for beverages such as coffee.
Partial replacement for vanilla in recipes calling for both vanilla and sugar

Home made Vanilla extract

Select your vanilla beans carefully, dark moist beans with plenty of aroma.

Chop 50 grams of beans crossways into about 5 mm pieces.

Add 500 mls of unflavoured vodka (40% alcohol).

Place  this mixture into a sealed jar or bottle to prevent evaporation.

The flavour will be leached out over a period of two weeks.

The mixture will clear and then you can decant the clear extract.

Food Product Design Vanilla +Other

 

 

What are the important aroma components in Natural Vanilla?

Well other than vanillin which is the number one aroma, guaicol is present in  small but significant amounts, it is a more powerful flavour than vanillin so contributes greatly to the overall flavour. Contrary to a belief that guaicol was derived from the smoke used to cure the beans the research below show it is a natural component of many varieties and ones that are not exposed to wood fires.

Natural vanilla contains a large number of other minor components that all add character  just as they do in great wines and spirits so duplicating natural vanilla is very difficult.

Most analysis of vanilla flavour I have cited are very poor! Vanilla contains many compounds that stick to the lining of capillary columns and hence are not detected.  (Para hydroxybenzaldehyde)

Vanilla analysis comparison of beans  This is fairly impressive but has some missing components, but skip the funnies first!

Vanilla Secrets

I have studied vanilla for a number of years now and read most of the reports. Rather than repeating the information in the above links by numerous authors I will just add my thoughts. So remember to read the links first.

Green vanilla beans contain about 85% water and 1% Vanillin present as a glucoside. Vanilla is cured by blanching the beans at 65 to 70 deg C for 2 minutes and then wrapped in a blanket to induce “sweating” ( The Bourbon Process)

There is very little scientific reasoning for this process, but tradition indicates it works.

Vanilla like a lot of fruits contains a triglyceride and this is what makes the beans shine (after curing). When vanilla beans are extracted  a 55% alcohol solution is used and this dose not extract the oil as it is insoluble in this strength alcohol. Anyone who has extracted beans to make a vanilla essence will have noticed this oil.

It may be that this dipping is to break the oil/wax outer layer to allow the fruit to dry quicker?

This process is mainly (also) used  to allow the natural enzyme to free the vanillin from the glucoside. The enzyme process works best at around 50 deg C. Now it takes 5 kg of green beans to produce 1 kg of cured beans, normally these cured beans contain only 1.8% vanillin when they should have around 5% vanillin. Vanillin is lost to evaporation.

Now traditionally woolen blankets were used in the process and now polyester ones are used. My theory is that the woolen blankets let the moisture through but retained the vanillin while the new synthetic blankets did not do the job properly.

Wool is  a great material for adsorbing odors', synthetic is not a good absorber.

In case you did not read the links. Beans were wrapped in blankets and stored in boxes overnight and at midday each day were opened and exposed to the sun. This allowed the water to evaporate and heated the beans back to around 50 deg C. The beans were then wrapped again and taken back to be stored overnight. This goes on for several months until most of the water had evaporated and the maximum level of vanillin was formed. UV from the sun also helped reduce the mould.

However this skilled process was not carried out correctly in recent years leading to a poorer quality product. Synthetic blankets were part of the problem as well as lack of experience and using the Mexican method..

There are now fast curing methods that “dry” the beans fast but do little to prevent the loss of natural vanillin.

 

 

Bo Jensen’s says:

Vanillin, or 4-hydroxy-3-methoxybenzaldehyde, is by far the major odorant from vanilla, but several additional aroma compounds are formed during the curing process (more than 100 are identified). Guaicol, creosol, acetovanillone, vanillyl alcohol and methyl salicylate seem to be of importance, together with vitispiranes